Exclusion list (Registry):
Software\Microsoft\Windows\CurrentVersion\Internet Settings\5.0\Cache\Extensible Cache\EmieUserList (IE11 Enterprise Mode)
Software\Microsoft\Windows\CurrentVersion\Internet Settings\5.0\Cache\Extensible Cache\EmieSiteList (IE11 Enterprise Mode)
Software\Microsoft\Internet Explorer\DomainSuggestion (IE11 Enterprise Mode)
Software\Microsoft\AppV\Client\Publishing
Software\Microsoft\AppV\Client\Integration

 

Directories to synchronize:
appdata\roaming\microsoft\windows\start menu
appdata\roaming\microsoft\systemcertificates
appdata\roaming\microsoft\protect
appdata\roaming\microsoft\internet explorer
appdata\roaming\microsoft\crypto
appdata\roaming\microsoft\credentials
appdata\local\microsoft\credentials
appdata\locallow\sun\java\deployment\security
appdata\locallow\sun\java\deployment\ext
Appdata\LocalLow\sun\java\deployment
appdata\local\packages
appdata\local\microsoft\windows\caches
AppData\Roaming\Mozilla

 

Files to synchronize:
appdata\locallow\sun\java\deployment\deployment.properties
appdata\locallow\google\googleearth\*.kml
appdata\local\tiledatalayer\database\vedatamodel.edb
appdata\local\microsoft\windows\usrclass.dat*
appdata\local\microsoft\office\*.qat
appdata\local\microsoft\office\*.officeui
AppData\LocalLow\Sun\Java\Deployment\deployment.properties
AppData\LocalLow\Sun\Java\Deployment\security\exception.sites
AppData\LocalLow\Sun\Java\Deployment\security\trusted.certs
AppData\Local\Google\Chrome\User Data\First Run
AppData\Local\Google\Chrome\User Data\Local State
AppData\Local\Google\Chrome\User Data\Default\Bookmarks
AppData\Local\Google\Chrome\User Data\Default\Favicons
AppData\Local\Google\Chrome\User Data\Default\History
AppData\Local\Google\Chrome\User Data\Default\Preferences

 

Exclusion list – Directories:
videos
tracing
saved games
pictures
onedrive
music
java
favorites
downloads
documents
citrix
Sharefile
appdata\roaming\sun\java\deployment\tmp
appdata\roaming\sun\java\deployment\log
appdata\roaming\sun\java\deployment\cache
appdata\roaming\softcomputer
appdata\roaming\nuance\naturallyspeaking12
appdata\roaming\mozilla\firefox\profiles\*\sessionstore.bak
appdata\roaming\microsoft\appv\client\catalog
appdata\roaming\macromedia\flash player\macromedia.com\support\flashplayer\sys
appdata\roaming\macromedia\flash player\#sharedobject
appdata\roaming\icaclient\cache
appdata\locallow
appdata\local\windows live
appdata\local\temp
appdata\local\sun
appdata\local\microsoft\windows\notifications
AppData\Local\Microsoft\Windows\INetCache
appdata\local\microsoft\windows\cd burning
appdata\local\microsoft\windows\burn
appdata\local\microsoft\windows\application shortcuts
appdata\local\microsoft\windows live contacts
appdata\local\microsoft\windows live
appdata\local\microsoft\uev
appdata\local\microsoft\terminal server client
appdata\local\microsoft\outlook
appdata\local\microsoft\onenote
appdata\local\microsoft\onedrive
appdata\local\microsoft\office\15.0\lync\tracing
appdata\local\microsoft\messenger
appdata\local\microsoft\internet explorer\recovery
appdata\local\microsoft\internet explorer\emieuserlist
appdata\local\microsoft\internet explorer\emiesitelist
appdata\local\microsoft\internet explorer\emiebrowsermodelist
appdata\local\microsoft\appv
appdata\local\grouppolicy
appdata\local\google\chrome\user data\default\jumplisticonsold
appdata\local\google\chrome\user data\default\jumplisticons
appdata\local\google\chrome\user data\default\cached theme images
appdata\local\google\chrome\user data\default\cache
$recycle.bin
AppData\Roaming\Mozilla\Crash Reports
!ctx_localappdata!\Microsoft\Office\15.0\Licensing (Office 365 with Shared Computer Activation)
!ctx_localappdata!\Microsoft\Office\16.0\Licensing (Office 365 with Shared Computer Activation)
appdata\local\microsoft\internet explorer\emieuserlist (IE11 Enterprise Mode)
appdata\local\microsoft\internet explorer\emiesitelist (IE11 Enterprise Mode)
appdata\local\microsoft\internet explorer\emiebrowsermodelist (IE11 Enterprise Mode)
!ctx_localappdata!\Citrix\DriveMapper3
AppData\Local\Microsoft\Windows\Themes
AppData\Local\Microsoft\Windows\WebCache.old
AppData\Roaming\Microsoft\Internet Explorer\UserData
AppData\Roaming\Microsoft\Templates

 

Exclusion list – Files:
*thumb*.db
*icon*.db
!ctx_localappdata!\Microsoft\Windows\UsrClass.dat*
AppData\Roaming\Microsoft\Word\*.tmp
AppData\Roaming\Microsoft\Word\*.wbk

 

Folders to Mirror:
appdata\local\microsoft\vault
appdata\local\microsoft\windows\inetcookies
appdata\local\microsoft\windows\webcache
appdata\local\tiledatalayer
appdata\roaming\microsoft\windows\cookies

References

Java Properties not Saved to the User Profile

https://support.citrix.com/article/CTX130665How to save the tollbar customization on the user profile manager store

Create your Outlook auto-signature once with User Profile Manager